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View Notes - CHAPTER 09 - Benzene and its Derivatives.pdf from OCH 3 at University of Santo Tomas. �F@��p���:` *@O�#�+4� = $ �y@�C� �8���&���ߴ=Ϋ]���v���y.�m�uP��d�6,o���u�}�A��Dzl^Ed��m��a�!/I�#r��s�����f���Rե������@����@��o�|�r}P�(s���m����-c+V��wkU����*�Ȥ6צһM�����g�v�H��lf��qqa>ʓ|2���p�Wwċ�:ED�\z9��Q^�٧�!=��X��s��b�%3����� $M{�kx'ʜt�35n�a��b]���Cu��F�d+s����wZ"74P�c�6��{�#aW|6������zR{x4L�{���n��gf�Xg�70[��ܧJT�k⤖�E�_��}{�^4�39�'O|Y�1 x�b```f``z�����v�A�X�����x������ �0d`j``�)Ux�ͭ�V�����ǜY��np�3Y0. Benzene and its Derivatives PDF Note Download Free for Pharmacy students. endstream endobj 650 0 obj <> endobj 651 0 obj <> endobj 652 0 obj <>stream ` ���� o:�� U�������o���s~�wν3 AKTU B Pharm Question Papers Download – 2020, Helpful Physical Pharmacy Notes Free Download-2020, Pharmaceutical Engineering Notes Free PDF Download. 268 18 of benzene, Orbital picture, resonance in benzene, aromatic. characters, Huckel’s rule Benzene & Its Derivatives Chapter 22 Organic Lecture Series 2 Reactions of Benzene The most characteristic reaction of aromatic compounds is substitution at a ring carbon: + + Chlorobenzene Halogenation: H Cl2 Cl FeCl3 HCl + + Nitrobenzene Nitration: HNOHNO3 2 H2 SO4 H2 O Create Date August 19, 2020. %%EOF Lecture Notes Chem 51B S. King Chapter 17 Benzene and Aromatic Compounds I. 268 0 obj <> endobj %%EOF 0 • The dashed lines inside the hexagon in the resonance hybrid of benzene O��Q^v�!�!��UI_۷�[�3_e���cBÌ��c�����ۍ�~������-`֧]P�}N���W%�I�8�_��Fj� 7�3]1�ھ�ۆ�ދdv�s�\)�$�d�ԭ\�Ӌ���>�;}͟{��&C�0���HtIk����}��6*H��м��\�����݁���(��BK��{l��[�)ʨ���R�m 0000001632 00000 n 0000003098 00000 n Download 6. %PDF-1.5 %���� benzene and derivatives members group : nur hidayah badaruddin syazana ismailnoor azurah abdul razak ira nusrat jaafar nor fadilah zakaria 2. 0000002868 00000 n 0000005686 00000 n These have been made according to the syllabus 9701 and cover all the relevant topics for examination in March/June. 26: Benzene and Its Compounds. startxref 649 0 obj <> endobj Benzene and its Derivatives PDF Note Download Free for Pharmacy students. Friedelcrafts alkylation- reactivity, limitations, of benzene, Orbital picture, resonance in benzene, aromatic Benzene and its Derivatives PDF Note Download. %PDF-1.4 %���� trailer <]>> 8��q����`�Oxwa&e�r���*�ʩQ�6�-��D���3�){�Uϙ�0�>|�.� �G�-FQ8Й� ���u�4�`�.� �3� �~E���H�Q�0�,@�� �m�e�`��Q��N� ���` �\ F�`��F8���b@E�E��w!Ma �C�S紎ʇj(�2��@>�㙹�� ��d`��. 0000005462 00000 n Reactions of benzene - nitration, sulphonation, halogenationreactivity, 0000002548 00000 n 697 0 obj <>stream endstream endobj startxref 0000004896 00000 n The Structure of Benzene • In the resonance hybrid, the six electrons from the three π-bonds are delocalized over the entire ring. 0000000016 00000 n h�bbd```b`�6�� �QDr��� �IDJ:���A�(X�ɢ&o�H�0;���+A��"��e`��l�l ����D2���{����30120I����8 ���7 1�| Download Benzene and its Derivatives. Write the oxidation of the benzylic groups with C-H bond(s) to benzoic acid. 0000002585 00000 n 675 0 obj <>/Filter/FlateDecode/ID[<7019F9F791D6EE04476CF255454BC31E>]/Index[649 49]/Info 648 0 R/Length 124/Prev 912442/Root 650 0 R/Size 698/Type/XRef/W[1 3 1]>>stream Name benzene derivatives. Notes for the CIE O Level Chemistry – 26: Benzene and Its Compounds. 0 Version 1. CHAPTER 09 Benzene and its Derivatives Modified and prepared by: Robert Dominic D. … 0000006275 00000 n ����D�hL���Gc$�{w����;q�8�y������E\%y�4��Za��z �|sʆqZ*l�0z{u�w_�'j��'f~w�uoUL�ު�n����ƃd8T�����!|QEy����CuS(�|Z�0�WP&P�{��JF7dI���a:W�Y?$�H��+�*�X�؏'��&��7q���IbH�s�ކC�-��dR;L��?\�x%v�������{�'�I��o��Yp�u. 0000000656 00000 n 3. The Phenyl Group (The Foundation of Benzene Derivatives) The phenyl group is formed by removing one hydrogen from benzene to create the fragment is C 6 H 5. 0000009220 00000 n Friedelcrafts acylation. 2. 285 0 obj <>stream INTRODUCTION• Benzene is a chemical that is a colourless or light yellow liquid at room temperature. A. Kekulé’s Model of Benzene The first structure for benzene, proposed by August Kekulé in 1872, consisted of a six-membered ring with alternating single and double bonds and with one hydrogen bonded to each carbon. B. Explain the trend for the acidity of substituted phenol using the concept of electron-donating and electron-withdrawing groups, and inductive and resonance effects.. 4. ?�E}���\T������ ��W Recognize aromatic compounds using Huckel's criteria. #��}�7�q���mÄ[�^�hܦ�����+� ��C>�~ �uX`��"��5��J�K�X[G$�Tq7��oU��}��=�|'�t&'�R�X>������ra�� �����t����5�̣�y7����~��Wk���ꠓUK1�b���4 V����KEY#q�ۺ��3@(�H 0000001262 00000 n xref 0000001481 00000 n 0000002023 00000 n File Size 0.00 KB. 2ӊ�(]����_�/hz���&?���˫ŝ��l?�V�������s��z��̬Z�!�]�6Co��ܤ���)��uK���%��g�� K�L���O������"�H����T>i� 15.3: Structure and Stability of Benzene Formula: C 6H 6, four degrees of unsaturation (section 6.2) three double bonds + one ring The π-bonds of benzene are resistant to the normal reactions of alkenes and alkynes Br Br Cl CHO CHO Br 2 HCl O 3 No Reaction Benzene’s cyclic conjugated structure gives it … Analytical, synthetic and other evidences in the derivation of structure.
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