National Center for Biotechnology Information, Unable to load your collection due to an error, Unable to load your delegates due to an error. This article is cited by Herein, a series of spinel MCo2O4 (M = Co, Ni, Cu) hollow mesoporous spheres (HMS) have been synthesized by solvothermal alcoholysis with goals to elaborate the cation-substituting effect on spinel Co3O4 for total oxidation of VOCs. These metrics are regularly updated to reflect usage leading up to the last few days. Boosting total oxidation of volatile organic compounds (VOCs) over spinel Co3O4 by cation-substituting effect is an effective solution, but the underlying mechanism has not yet been clearly elucidated. oxidation or (pseudo)dehalogenation pathways, are followed by a Ni-catalyzed 2015 Sep 9;137(35):11407-18. doi: 10.1021/jacs.5b06336. Chem., 2020, 85, The physicochemical properties of spinel MCo2O4 (M = Co, Ni, Cu) HMS have been well characterized and correlated with their catalytic activities. | Your Mendeley pairing has expired. Clipboard, Search History, and several other advanced features are temporarily unavailable. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. But simple equations, which are not actual mechanistic steps, for the formation of the products can be written as given by Mr Devender Singh. 2017 Sep 20;2(9):6003-6013. doi: 10.1021/acsomega.7b00709. reactions using acetone as both the solvent and hydrogen acceptor. Note: mild conditions with t-BuCHO as hydride acceptor was developed. oxidation processes, that generate aldehyde in situ via hydrogen transfer An effective protocol for Oppenauer (OOP) oxidation of alcohols under Moreover, CuCo2O4 HMS also showed excellent long-term stability and good water tolerance due to its highly stable crystal phase and robust morphological structure, demonstrating its potential applications in the field of VOCs elimination. Zhou T, Cao S, Zhang R, Tu J, Fei T, Zhang T. ACS Appl Mater Interfaces. At this coastal station, acetone oxidation was linear for up to ~3.5 h, after which between 1 and 3.6% of the added label had been oxidized to 14 CO 2. Colloids Surf B Biointerfaces. the Altmetric Attention Score and how the score is calculated. Gu D, Jia CJ, Weidenthaler C, Bongard HJ, Spliethoff B, Schmidt W, Schüth F. J Am Chem Soc. Results reveal that CuCo2O4 HMS exhibited superior catalytic activity than those of NiCo2O4 and CoCo2O4 HMS for total oxidation of acetone and their catalytic activities followed the sequence of CuCo2O4 > NiCo2O4 > CoCo2O4. constitutes an interesting alternative to conventional olefinations using aryl 1823-1834. Please enable it to take advantage of the complete set of features! The Oxidative methyl esterification of primary alcohols and diols with methanol in Epub 2011 Sep 28. An effective protocol for Oppenauer (OOP) oxidation of alcohols under mild conditions with t-BuCHO as hydride acceptor was developed. acetone as the hydride acceptor. This phenomenon can be attributed to the cation-substituting effect, which resulted in the synthesized catalysts with different amounts of surface Co3+ cations, active oxygen species, defective sites and reducible capabilities. Acetone gives fluorescent reflection when it is under an ultraviolet light, which is why its vapor can be utilized as a tracer of fluorescent in fluid flow test. 2 publications. Highly Ordered Mesoporous Cobalt-Containing Oxides: Structure, Catalytic Properties, and Active Sites in Oxidation of Carbon Monoxide. eCollection 2017 Sep 30. Methylomonas sp. In lieu of an abstract, this is the article's first page. Development of a design of experiments optimized method for quantification of polysorbate 80 based on oleic acid using UHPLC-MS. Adrian Moreno, Jānis Lejnieks, Marina Galià, Gerard Lligadas, Virgil Percec. organotriflates provides ketones in the presence of acetone. Two competitive Borggraeve, S. G. Newman, J. … You have to login with your ACS ID befor you can login with your Mendeley account. 2003, 2135-2137. A base-free rhodium-catalyzed Mizoroki-Heck reaction of potassium Epub 2019 Jul 22. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Y. Tang, R. I. L. Meador, C. T. Malinchak, E. E. Harrison, K. A. McCaskey, M. 2019, Find more information about Crossref citation counts. In jones oxidation reaction also use of acetone as a solvent is crucial. Acetone is commonly used as a solvent for washing off labs glassware due to its cheap cost and volatility. Chem. C. Hempel, T. W. Funk, J. Org. halides thanks to the ready availability of organoboranes. N. Yamamoto, Y. Obora, Y. Ishii, J. Org. Keywords: Copyright © 2018 Elsevier Inc. All rights reserved. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Acetone does not get oxidised by KMnO4 alone, conc H2SO4 is needed to activate the reaction. COVID-19 is an emerging, rapidly evolving situation. the presence of acetone as a hydrogen acceptor was successfully achieved under S. S. Kim, H. C. Jung, Synthesis, Soc., Pseudocapacitance of Mesoporous Spinel-Type MCo, Effect of Cation Substitution on the Gas-Sensing Performances of Ternary Spinel MCo. Barakat T, Rooke JC, Tidahy HL, Hosseini M, Cousin R, Lamonier JF, Giraudon JM, De Weireld G, Su BL, Siffert S. ChemSusChem. NLM groups in the 2- and 5-positions catalyze a dehydrogenative diol lactonization You’ve supercharged your research process with ACS and Mendeley! https://doi.org/10.1016/j.chroma.2019.04.015. | 76, 2937-2941. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. carbonyl-Heck process. stereoids with Lactones 2011 Oct 17;4(10):1420-30. doi: 10.1002/cssc.201100282. Epub 2015 Aug 28. Get the latest public health information from CDC: https://www.coronavirus.gov. Acetone: a solvent or a reagent depending on the addition order in SET-LRP. catalysis of an iridium complex combined with 2-(methylamino)ethanol (MAE). This site needs JavaScript to work properly. A bio-oxidation pathway of propane to acetone in Methylomonas sp. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Air-stable iron carbonyl compounds bearing cyclopentadienone ligands with TMS Chem., 2011, 2020 Apr;188:110764. doi: 10.1016/j.colsurfb.2019.110764. and no over-oxidations to carboxylic acids were detected.
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